Catalysis of cycloaddition reactions

Keywords :

aromatic skeletons, [2+2+2] cycloadditions, cycloisomerization, heterocycles, Ru- and Rh-catalysis, biologically active compounds

Members:

• Virginie Vidal| 📧
• Mansour Haddad| 📧

Selected recent publications:

1. W. Parisot, M. Haddad, P. Phansavath, G. Lefèvre, V. Ratovelomanana-Vidal, A Versatile, Functional Group-Tolerant, and Bench-Stable Iron Precatalyst for Building Arene and Triazine Rings by [2+2+2] Cycloadditions, Chem. Eur. J. 2024, 30, e202400096.
2. W. Parisot, S. Huvelle, M. Hadadd, G. Lefèvre, P. Phansavath, V. Ratovelomanana-Vidal, Synthesis of 5H-chromeno[3,4-c]pyridine derivatives through ruthenium-catalyzed [2 + 2 + 2] cycloaddition, Org. Chem. Front. 2023, 10, 1309-1315.
3. S. Huvelle, P. Matton, C. Tran, M.−N. Rager, M. Haddad, V. Ratovelomanana-Vidal, Synthesis of Benzo[c][2,7]naphthyridinones and Benzo[c][2,6]naphthyridinones via Ruthenium−Catalyzed [2 + 2 + 2] Cycloaddition between 1,7−Diynes and Cyanamides, Org. Lett. 2022, 24, 5126−5131.
4. P. Matton, S. Huvelle, M. Haddad, P. Phansavath, V. Ratovelomanana-Vidal,Recent Progress in Metal-Catalyzed [2+2+2] Cycloaddition Reactions, Synthesis 2022, 54, 4–32.
5. F. Ye, M. Haddad, V. Ratovelomanana-Vidal, V. Michelet, Org. Lett. 2017, 19, 1104. “Ruthenium-Catalyzed [2+2+2] Cycloaddition Reaction Forming 2-Aminopyridine Derivatives from α,ω-Diynes and Cyanamides”
6. F. Ye, C. Tran, L. Jullien, T. Le Saux, M. Haddad, V. Michelet, V. Ratovelomanana-Vidal « Synthesis of Fluorescent Azafluorenones and Derivatives via a Ruthenium-Catalysed [2+2+2] Cycloaddition Org. Lett. 2018, 20, 4950-4953.